Solapur University M Sc Chemistry Entrance Exam

Can you provide me the syllabus of M. Sc. Part-II (Analytical Chemistry) of University of Solapur as I want to check it before taking admission in the course?

[Pathak]

Solapur University located in Solapur city in Maharashtra state which was inaugurated on 3 August 2004. The jurisdiction of the university is spread over Solapur district, with a strength of about 60,000 student studying in 119 affiliated colleges and recognized institutes

M Sc Chemistry Syllabus

CH-ANAL-301

Advance Separation Techniques-I

Unit-I

Paper Chromatography-Definition, theory and principle, techniques, one, two dimensional and circular paper chromatography, mechanism of separation, structure of cellulose and types of paper, methodology-separation of sample, choice of solvents, location of spots and measurement of Rf value, factors affecting Rf value, advantages and applications.

Affinity Chromatography- Introduction, theory stationary phase, preparation of column, separation of antigens.

Exclusion Chromatography- Theory and principle of size exclusion chromatography, experimental techniques for gel filtration chromatography (GFC) and gel-permeation chromatography (GPC), materials for packing-factors governing column efficiency, methodology and applications.

Unit-II
Electrophoresis-Theory and classification, factors affecting mobility, macromolecular size and charge interactions with supporting electrolyte, pH and concentration discontinuities, Factors affecting electrophoresis phenomena-electrolysis, electrosomosis, temperature and supporting media. Instrumentation, methodology, Preparation of gelstaining and destaining, preparative zone electrophoresis, continuous electrophoresis and Applications.

Capillary Electrophoresis-Principle, theory, instrumentation, sample preparation and applications, Capillary electrochromatography and Miscellar electrokinetic capillary chromatography

Unit-III
Membrane-Based Methods:-Dialysis-working of techniques, membranes, general consideration of diffusion, Donnan Membrane equilibrium and Applications. Electrodialysis- working of techniques, membranes, Electrodialysis cells and Applications.

Ultrafiltration- working of techniques, membranes, non-gelatinous membranes and Applications. Dialysis compared with other membrane-separation methods. Other Separation Methods:-Ultracentrifugation-Principle, sedimentation constant, sedimentation equilibrium, sedimentation velocity, methodology and applications. Zone refining- Principle, zone leveling and applications.

Unit-IV
Solvent Extraction- Basic principles, classification of solvent exaction systems, Factors affecting extraction process, Mechanism of extraction, extraction by chelation extraction by solvation, extraction equilibria for chelates, extraction equilibria for solvation, techniques of extraction, separation of metals by extraction, extraction by ion-pair formation, application of solvent extraction in industry, solid-phase extraction (SPE) and uses.

M Sc Chemistry Syllabus
Unit-I 12
Paper Chromatography-Definition, theory and principle, techniques, one, two
dimensional and circular paper chromatography, mechanism of separation, structure of
cellulose and types of paper, methodology-separation of sample, choice of solvents,
location of spots and measurement of Rf value, factors affecting Rf value, advantages and
applications.
Affinity Chromatography- Introduction, theory stationary phase, preparation of column,
separation of antigens.
Exclusion Chromatography- Theory and principle of size exclusion chromatography,
experimental techniques for gel filtration chromatography (GFC) and gel-permeation
chromatography (GPC), materials for packing-factors governing column efficiency,
methodology and applications.
Unit-II 12
Electrophoresis-Theory and classification, factors affecting mobility, macromolecular
size and charge interactions with supporting electrolyte, pH and concentration
discontinuities, Factors affecting electrophoresis phenomena-electrolysis, electrosomosis,
temperature and supporting media. Instrumentation, methodology, Preparation of gelstaining
and destaining, preparative zone electrophoresis, continuous electrophoresis and
Applications.
Capillary Electrophoresis-Principle, theory, instrumentation, sample preparation and
applications, Capillary electrochromatography and Miscellar electrokinetic capillary
chromatography
Unit-III 12
Membrane-Based Methods:-Dialysis-working of techniques, membranes, general
consideration of diffusion, Donnan Membrane equilibrium and Applications.
Electrodialysis- working of techniques, membranes, Electrodialysis cells and
Applications.
Ultrafiltration- working of techniques, membranes, non-gelatinous membranes and
Applications. Dialysis compared with other membrane-separation methods.
Other Separation Methods:-Ultracentrifugation-Principle, sedimentation constant,
sedimentation equilibrium, sedimentation velocity, methodology and applications.
Zone refining- Principle, zone leveling and applications.
Unit-IV 12
Solvent Extraction- Basic principles, classification of solvent exaction systems, Factors
affecting extraction process, Mechanism of extraction, extraction by chelation extraction
by solvation, extraction equilibria for chelates, extraction equilibria for solvation,
techniques of extraction, separation of metals by extraction, extraction by ion-pair
formation, application of solvent extraction in industry, solid-phase extraction (SPE) and
uses.
References
1. Solvent Extraction in Analytical Chemistry. By G H Morrison and H Freiser (
John Wiely New York, 1958)
2. Solvent Extraction of metals by A K Da, S M Khopkar and R A Clalmers. (Von
Nonstrant Ravinhold, 1970)
3. A Textbook of Inorganic Qualitative Analysis. By A I Vogel.
4. Chromatography. By E Heftman, 5th edition, part-A and part-B, Elsewhere
Science Publisher, 1992.
5. Chromatography Today. By C F Poole and S K Poole, Elsewhere Science
Publisher, 1991.
6. Electrophoresis- Analytical Chemistry. Open Learning by M Melvin John
Wiley and Sons.1987.
7. Analytical Chemistry. By G D Christian 4th edition, John Wiley and Sons, 1986.
8. Instrumental Methods of Analysis, by B K Sharma, 19th edition, Goel
Pubisher,2000.
9. Basic Concept in Analytical chemistry, by S.M. Khopkar.
Unit-I 12
Thermal Methods of Analysis-Introduction, thermo gravimetric analysis (TGA),types of
thermo gravimetric analysis, principle, factors affecting the results-heating rate, furnace,
instrument control/data. Application-purity and thermal stability, evaluation of correct
drying temperature, analysis of complex mixture and determination and kinetic
parameters of thermal degradation.
Differential Thermal Analysis(DTA)- Theory, variables affecting the DTA curves,
Difference between TGA and DTA. General principle, instrumentation, applications.
Analysis of physical mixtures and thermal behaviors study. Determination of melting
point, boiling point and decomposition point.
Differential Scanning Calorimetry (DSC)-Basic principal, difference between DTA
and DSC. Instrumentation-Power compressed DSC, Heat flux DSC. Applications-
Studies of thermal transition and isothermal crystallization. Thermometric titrations.
Unit-II 12
Radio Analytical Techniques-Determination of nuclear radiation and counting devices.
Radioactivity tracers- Principal and applications. Isotopic Analysis- direct and inverse.
Special analytical application-radiometric titrations. Neutron activation analysis: principle,
instrumentation, applications and limitations. Radiochromatography and Radioimmunoassay:
principle, instrumentation, applications and limitations.
Radiometric titration- principle, types, instrumentation and applications
Unit-III 12
Electro Analytical Techniques
1. Ion Selective Electrodes- Terminology, types and construction of selective electrodes glass
electrode, solid state and precipitate electrodes, liquid-liquid membrane electrode,
enzyme and glass-sensing electrodes, glass electrodes for pH measurement (glass micro
electrode) and applications
2. Voltametry and Stripping voltametry- Principle, instrumentation and applications. Cyclic
voltametry.
Electrogravimetric analysis- Theory, apparatus, cell process, deposition and separation,
electrolytic separation of metals and applications.
3. Coulometric Methods
Introduction, Principle, Coulometric techniques, potentiostatic couloumetry, Coulometric
titrations, Coulometric determination, Advantages, Instrumentation for coulometric titration
and applications.
Unit-IV 12
1. High frequency titration principle, instrumentation, advantages and disadvantages of
high frequency method. Applications acid-base, complxometric measurement dielectric
constant and analysis of mixture.
2. Ampherometry titration principles of Amperometric titrations, instrumentation, titration
procedure, advantages and disadvantages
3. Electrgravimetric titration principle & theory, methods of electrogravimetric analysis,
instrumentation, advantages and disadvantages

more syllabus detail attached a pdf file;