#1
25th July 2015, 08:37 AM
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MSC Chemistry Syllabus Kota University
Will you please provide here syllabus for M.Sc. (Previuos) Chemistry program of Kota University ?
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#2
25th July 2015, 03:49 PM
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Re: MSC Chemistry Syllabus Kota University
As you want I am here giving you syllabus for M.Sc. (Previuos) Chemistry program of Kota University. Syllabus : Inorganic Chemistry Organic Chemistry Physical Chemistry Group Theory & Spectroscopy Mathematics for chemists or Biology for Chemists Computers for Chemists Practical Seminar (Internal) INORGANIC CHEMISTRY Unit-I Stereochemistry and Bonding in Main Group Compounds VSEPRT, Walsh diagram (tri- and penta-atomic molecules), d_-p_ bonds, Bent rule and energetics of hybridization, some simple reactions of covalently bonded molecules. Metal-Ligand Equilibria in Solution Stepwise and overall formation constants and their interaction, trends in stepwise constant, factors affecting the stability of metal complexes with reference to the nature of metal ion and ligand. Chelate effect and its thermodynamic origin, determination of binary formation constants by pH-metry and spectrophotometry. Unit-II Reaction Mechanism of Transition Metal Complexes Energy profile of a reaction, reactivity of metal complex, inert and labile complexes, kinetic application of valence bond and crystal field theories, kinetics of octahedral substitution, acid hydrolysis, factors affecting acid hydrolysis, base hydrolysis, conjugate base mechanism, direct and indirect evidences in favour of conjugate mechanism, anation reactions, reactions without metal ligand bond cleavage. Substitution reactions in square planar complexes, the trans effect, mechanism of the substitution reaction. Redox reaction, electron transfer reactions, mechanism of one electron transfer reactions, outer sphere type reactions, cross reactions and Marcus-Hush theory, inner sphere type reactions. Unit-III Metal-Ligand bonding Limitation of crystal field theory, molecular orbital theory, octahedral, tetrahedral and square planar complexes, _-bonding and molecular orbital theory. Unit-IV Electronic Spectra and Magnetic Properties of Transition Metal Complexes Spectroscopic ground states, correlation. Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1-d9 states), calculations of D_, _ and _ parameters, charge transfer spectra, spectroscopic method of assignmetnt of absolute configuration in optically active metal chelates and their stereochemical information, anomalous magnetic moments, magnetic exchange coupling and spin crossover. Unit-V A. Metal _-Complexes Metal carboynl, structure and bonding, vibrational spectra of metal carbonyls for bonding and structural elucidation, important reactions of metal carbonyls; preparation, bonding structure and important reaction of transition metal nitrosyl, dinitrogen and dioxgen complexes; tertiary phosphine as ligand. B. Metal Clusters Higher boranes, carboranes, metalloboranes and metallocarboranes. Metal carbonyl and halide clusters, compounds with metal metal multiple bonds. M.Sc. (Previuos) Chemistry Syllabus kinetic requirements, kinetic and thermodynamic control, Hammond's postulate, Curtin-Hammett principle. Potential energy diagrams, transition states and intermediates, methods of determining mechanisms, isotopes effects Generation, structure, stability and reactivity of carbocations, carbanions, free radicals, carbenes and nitrenes. Effect of structure on reactivity, resonance and field effects, steric effect, quantitative treatment. The Hammett equation and linear free energy relationship, subsistent and reaction constants, Taft equation. B. Aliphatic Nucleophilic Substitution The SN2, SN1 mixed SN1 and SN2 and SET mechanisms. The neighbouring group mechanism, neighbouring group participation by _ and _ bonds, anchimeric assistance. Classical and nonclassical carbocations, phenonium ions, norbornyl systems, common carbocation rearrangements. Application of NMR spectroscopy in the detection of carbocations. The SN1 mechanism. Nucleophilic substitution at an allylic, aliphatic trigonal and a vinylic carbon. Reactivity effects of substrate structure, attacking nucleophile, leaving group and reaction medium, phase transfer catalysis and ultrasound, ambident nucleophile, regioselectivity. Unit-III Aliphatic Electrophilic Substitution Bimolecular mechanisms SE2 and SE1, The SE1 mechanism, electrophilic substution accompanied by double bond shifts. Effect of substrates, leaving groups and the solvent polarity on the reactivity. Aromatic Electrophilic Substitution The arenium ion mechanism, orientation and reactivity, energy profile diagrams. The ortho/para ratio, ipso attack, orientation in other ring systems. Quantitative treatment of reactivity in substrates and electrophiles. Diazonium coupling, Vilsmeir reactiion, Gatterman- Koch reaction. Aromatic Nucleophilic Substitution The SNAr SN1, benzyne and SRN1 mechanism, Reactivity effect of substrate structure, leaving group and attacking nucleophile. The Von Richte, Sommelet-Hauser, and Smiles rearrangements. Free Radical Reactions Types of free radical reactions, free radical substitution mechanism, mechanism at an aromatic substrate, neighbouring group assistance. Reactivity for aliphatic and aromatic substrates at a bridgehead. Reactivity in the attacking radicals. The effect of solvents on reactivity. Allylic halogenation (NBS), oxidation of aldehydes to carboyxlic acids, autooxidation, coupling of alkynes and arylation of aromatic compounds by diazonium salts, Sandmeyer reaction. Free radical rearrangement. Hunsdiecker reaction. Address: University of Kota Near Kabir Circle, MBS Marg, Swami Vivekanand Nagar Kota, Rajasthan 324005 Map: [MAP]University of Kota Rajasthan[/MAP] Here is the attachment; |
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