APPSC Organic Chemistry

Hello sir is there any one can provide me syllabus for APPSC Organic Chemistry. I want syllabus of APPSC Organic Chemistry for preparation so please provide me?

[sumit]

As per my searching I was founded syllabus of APPSC Organic Chemistry.

APPSC exam paper pattern:

Papers
PART-A: Written ‘Examination (Objective Type)
No.of Questions Duration(Minutes) Maximum Marks
Paper-1: General Studies 150 150 150
Paper-2: Concerned Subject 150 150 300

PART-B: Interview (Oral Test) 50

Here I’m attaching a PDF of syllabus of APPSC Organic Chemistry:

APPSC Organic chemistry syllabus:

1 Bonding and shapes of organic molecules: Electronegativity, electron displacements-inductive,mesomeric and hyperconjugative effects; bond polarity and bond polarizability, dipole moments of organic molecules; hydrogen bond; effects of solvent and structure on dissociation constants of acids and bases; bond formation, fission of covalent bonds; homolysis and heterolysis; reaction intermediates-carbocations, carbanions, free radicals and carbenes; generation geometry and stability; nucleophiles and electrophiles.


2 Chemistry of aliphatic compounds: Nomenclature alkanes-synthesis, reactions (free radical halogenation) – reactivity and selectivity, sulphonation-detergents; cycloalkanes-Baeyers’ strain theory; alkanes and alkynes-synthesis, electrohilic addition; reactions, Markownikov’s rule, peroxide effects, 1-3-dipolar addition; nucleophilic addition to electron-deficient alkenes; polymerization; relative acidity; synthesis and reactions of alkyl halides, alkanols, alkanals, alkanones, alkanoic acids, esters, amides, nitriles, amines, acid anhydrides, -unsatuarated ketones, ethers and nitro compounds.

3 Stereochemistry of carbon compounds: Elements of symmetry, chiral and achiral compounds.Fischer projection formulae; optical isomerism of lactic and tartaric acids, enantiomerism and diastereo-isomerism; configuration (relative and absolute); conformations of alkanes upto four carbons, cyclohexane and dimethylcyclo-hexanes their potential energy D,L and R,S notations of compounds containing chiral centers; projection formulae-Fischer, Newman and sawhorse of compounds containing two adjacent chiral centers; meso and dl-isomers, erythro and threo isomers; racemization and resolution; examples of homotopic, enantiotopic and diasteretopic atoms and groups in organic compounds, geometrical isomers; E and Z notations. Stero-chemistry of SN1, SN2,E1 and E2 reactions.

4 Organometallic compounds: Preparation and synthetic uses of Grignard reagents, alkyl lithium compounds.

5 Active methylene compounds: Diethyl malonate, ethyl acetoacetate. ethyl cyanoacetateapplications in organic synthesis; tautomerism (keto-enol).

6 Chemistry of aromatic compounds: Aromaticity; Huckel’s rule; electrophilic aromatic substitution-nitration, sulphonation, halogenation (nuclear and side chain), Friedel-Crafts alkylation and acylation, substituents effect; chemistry and reactivity of aromatic halides, phenols, nitro, diazo, diazonium and sulphonic acid derivatives, benzyne reactions.

7 Chemistry of biomolecules:
(i) Carobhydrates: Classification, reactions, structure of glucose,D,L-configuration, osazone formation; fructose and sucrose; step-up step-down of aldoses and ketoses; and their interconversion,
(ii) Amino acids: Essential amino acids; zwitterions, isoelectric point, polypeptides; proteins; methods of synthesis of -amino acids.
(iii) Elementary idea of oils, fats,soaps and detergents.

8. Basic principles and applications of- UV, visible, IR and NMR spectroscopy of simple organic molecules.