2023 2024 Student Forum > Management Forum > Main Forum

 
  #2  
19th June 2015, 08:55 AM
Super Moderator
 
Join Date: Apr 2013
Re: M.Sc Chemistry Syllabus of Nagpur University

As you are looking for the M.Sc Chemistry Syllabus of Nagpur University , here I am providing same for you .

Semester I
CH-101: Paper I (Inorganic Chemistry)
CH-102: Paper II (Organic Chemistry)
CH-103: Paper III (Physical Chemistry)
CH-104: Paper IV (Analytical Chemistry)
CH-105: Practical-I (Inorganic Chemistry)
CH-106: Practical-II (Physical Chemistry)
CH-107: Seminar-I

Semester II
CH-201: Paper V (Inorganic Chemistry)
CH-202: Paper VI (Organic Chemistry)
CH-203: Paper VII (Physical Chemistry)
CH-204: Paper VIII (Analytical Chemistry)
CH-205: Practical-III (Organic Chemistry)
CH-206: Practical-IV (Analytical Chemistry)
CH-207: Seminar-II

Semester III
CH-301: Paper IX (Spectroscopy)
CH-302: Paper X (Special I-Inorganic /Organic/ Physical/Analytical)
CH-303: Paper XI (Special II-Inorganic /Organic/ Physical/Analytical)
CH-304: Paper XII (Elective- Applied Analytical/ Nuclear/ Environmental
/Polymer/Medicinal )
CH-305: Practical V- Special (Inorganic /Organic/ Physical/Analytical)
CH-306: Practical VI–Elective (Applied Analytical/ Nuclear/ Environmental
/Polymer/Medicinal)
CH-307: Seminar-III

Semester IV
CH-401: Paper XIII (Spectroscopy)
CH-402: Paper XIV (Special I-Inorganic /Organic/ Physical/Analytical)
CH-403: Paper XV (Special II-Inorganic /Organic/ Physical/Analytical)
CH-404: Paper XVI (Elective- Applied Analytical/ Nuclear/ Environmental
/Polymer/Medicinal)
CH-405: Practical VII- Special (Inorganic /Organic/ Physical/Analytical)
CH-406: Practical VIII- Project
CH-407: Seminar-IV
Nagpur University M.Sc Chemistry Syllabus
A) Stereochemistry and Bonding in Main Group Compound: 5h
VSEPER-Shape of simple inorganic molecules and ions containing lone pairs, various stereo chemical rules and
resultant geometry of the compounds of non-transitional elements, short coming of VSEPR model. Bent’s rule
and energetics of hybridization.
B) Metal – Ligand Bonding: 10h
Crystal Field Theory: Splitting of d-orbital in tetragonal, square planar and trigonal bipyramid complexes.
John teller effect, spectrochemical series, nephelauxetic effect. Limitaion of crystal field theory. M.O.theory
for octahedral, tetrahedral & square planar complexes with and without π-bonding.
Unit-II
A) Metal – Ligand Equilibria in Solution: 5h
Stepwise and overall formation constants; trends in stepwise formation constants; factors affecting stability
of metal complexes with reference to nature of metal ion, ligand, chelate effect and thermodyanamic origin.
Determination of formation constant by :
(1) spectrophotometric method (Job’s and Mole ratio method)
(2) Potentiometric method (Irving-Rossotti Method)
B) Reaction Mechanism of Transition metal complexes: 10h
Energy Profile of a reaction, reactivity of metal complexes, Inert and Labile complexes, Kinetics of Octahedral
substitution: Acid hydrolysis, factors affecting acid hydrolysis, Stereochmistry of intermidiates in SN1 & SN2 ,
Base hydrolysis, Conjugate base mechanism, Direct and indirect evidences in favour of conjugate mechanism,
Annation reaction, reaction without metal-ligand bond breaking.
Unit-III: Cluster- I 15h
Boron hydrides: Classification, nomenclature, structure, bonding and topology of boranes, 4-digit coding (s, t,
y, x) numbers for higher boranes and their utilities. Chemistry of diboranes: Study of Metalloboranes,
Carboranes and Metallocarboranes with reference to preparations and structures.
Unit – IV: Cluster-II
A) Metal-Metal bonds: 10h
Occurrence of metal-metal bond, Classification of metal clusters, Binuclear, trinuclear, tetranuclear,
pentanuclear and hexanuclear with reference to halide, oxide, alkoxide and acetate clusters.
B) Isopoly, Heteropoly acids and their anions. 5h
List of Books
1) S. F. A. Kettle, J. N. Murral and S. T. Teddler: Valency Theory
2) C. A. Coulson: Valency
3) J. E. Huheey :Inorganic Chemistry
4) F .A. Cottonand G. Wilkinson: Advanced Inorganic Chemistry 3rd, 5thand 6th Editions.
5) A. F. Willims: Theoretical Approach in inorganic chemistry.
6) A. Mannas Chanda: Atomic Structure and chemical Bonding
7) L. E. Orgel: An Introduction To transition metal chemistry, Ligand field theory, 2nd Edition.
8) J. J. Logowski: Modern Inorganic Chemistry
9) B.Durrant and P.J.Durrant: Advanced Inorganic Chemistry
10) J. C. Bailar: Chemistry of coordination compounds.
11) W. L. Jolly: Modern Inorganic Chemistry
12) R. S. Drago: Physical methods in inorganic chemistry.
13) Waddington: Nonaqueous solvents.
14) Sisler: Chemistry of nonaqueous solvents.
15) A. K. Barnard: Therotical Inorganic Chemistry
16) Emeleus and Sharpe: Modern Aspect of Inorganic Chemistry.
17) F. A. Cotton: Chemical Applications of Group theory.
18) Jones: Elementary Coordination chemistry.
19) B. N. Figgis: Introduction to Ligand field.
20) S. F. A. Kettle: Coordination chemistry.
21) M.C.Day and J.Selbin: Theoretical Inorganic Chemistry.
22) J. Lewin and Wilkins: Modern Coordination Chemistry.
23) Gowarikar, Vishwanathan and Sheedar: Polymer science.
24) H. H. Jattey and M. Orchin: Symmetry in chemistry.
25) D. Schonaland: Molecular Symmetry in chemistry.
26) L. H. Hall: Group theory and Symmetry in chemistry
27) H. H. Jattey and M. Orchin: Symmetry in chemistry
28) R.L.Dutta and A.Symal: Elements of magneto chemistry
29) Inorganic Chemistry 4th Edition, P.Atkins, Oxford University Press.
30) Essential Trends in Inorganic Chemistry, D.M.P.Mingos, Oxford University Press
Unit-I: 15 h
A] Nature and Bonding in Organic Molecule
Delocalized chemical bonding, conjugation, cross conjugation, resonance, hyper-conjugation, bonding in
fullerenes. Aromaticity in benzenoid and non-benzenoid compounds, alternant and non-alternant
hydrocarbons Huckel’s rule, energy level of π-molecules orbitals, annulenes, antiaromaticity, homoaromoaticity.
Aromatic character and chemistry of cyclopentadienyl anion, tropylium cation, tropone and
tropolone. Bonds weaker than covalent-addition compounds, crown ether complexes and cryptands,
inclusion compounds, cyclodextrins, catenanes and rotaxanes
B] Synthetic applications of enamines and imines anions in organic synthesis, phase transfer catalysis, crown
ethers and graphene.
Unit-II: 15 h
A] Streochemistry
Conformational analysis of cycloalkanes (5 – 8 membered rings), substituted cyclohexanes , mono
substituted, disubstituted and trisubstituted cyclohexanes, decalines, effect of conformation on reactivity,
Cahn-Ingold-Prelog System to describe configuration at chiral centers . Elements of symmetry, chirality,
molecules with more than one chiral center, meso compounds, threo and erythro isomers, method of
resolution, optical purity, enantiotopic and distereotopic atoms, groups and faces, prochirality, additionelimination
reactions, stereospecific and steroselective synthesis. Asymmetrical synthesis, optical activity in
absence of chiral carbon (biphenyl and allenes)
B] Reactive Intermediates
Generation, structure, stability and chemical reactions involving classical and non-classical carbocations,
carbanions, free radical, carbenes, nitrenes and arynes. Singlet oxygen, it’s generation and reactions with
organic substrates.
Unit-III: 15 h
A] Reaction mechanism: Structure and Reactivity
Types of mechanism, Types of reaction, thermodynamics and kinetics requirements, kinetic and
thermodynamic control, Hammond’s postulate, Curtin-Hammeett principle, Potential energy diagrams,
transition states and intermediates, methods of determining mechanisms, isotope effects. Hard and soft
acids and bases.
6
Effect of Structure on reactivity: Resonance and field effects, Steric effect, quantitative treatment. The
Hammett equation and linear free energy relationship, substituent and reaction constants. Taft Equation.
B] Concept of neighboring group participation (anchimeric assistance) with mechanism, neighboring group
participation by π and σ bonds, classical and non classical carbocations, Intramolecular displacement by
hydrogen, oxygen, nitrogen, sulphur and halogen. Alkyl, cycloalkyl, aryl participation, participation in bicyclic
system, migartory aptitude, carbocation rearrangements and related rearrangements in neighboring group
participation.
Unit IV: 15h
A] Aliphatic nucleophilic substitution
The SN1, SN2, mixed SN1, SN2 and SET and SNi mechanisms. Nucleophilicty, effect of leaving group, ambient
nucleophiles and ambient substrates regiospecificity, substitution at allylic and vinylic carbon atoms.
B] Aromatic electrophilic substitution
The arenium ion mechanism, orientation and reactivity, energy profile diagrams. The o/p ratio, ipso attack,
orientation in benzene ring with more than one substituents, orientation in other ring system. Diazonium
coupling, Vilsmeir reaction, Gatterman-Koch reaction, Pechman reaction, Reimer-Tieman reaction, Diazonium
coupling.
C] Aromatic Nucleophilic Substitution
A general introduction to different mechanisms of aromatic nucleophilic substitution SNAr, SN1, benzyne and
SRN1 mechanisms. Reactivity - effect of substrate structure leaving group and attacking nucleophile. The Von
Richter, Sommlet-Hauser and Smiles rearrangements.
List of books
1] Advanced Organic Chemistry –Reaction mechanism and structure. Jerry March, John Wiley
2] Advanced Organic Chemistry- F.A. Carey and R. J. Sunberg, Plenum
3] A Guidebook to Mechanism in Organic Chemistry-Peter Skyes, Longman
4] Structure and Mechanism in Organic Chemistry-C.K. Gold, Cornell University Press
5] Organic Chemistry, R.T. Morrison Boyd. Prentice Hall
6] Modern Organic Chemistry-H.O. House, Benjamin
7] Principal of Organic Chemistry-R.O.C. Norman and J.M. Coxon, Blackie Academic and Professional
8] Reaction Mechanism in Organic Chemistry-S.M. Mukharji and S.P. Singh, Macmilan
9] Stereochemistry of Organic Compounds- D. Nasipuri, New Age International
10] Stereochemistry of Organic Compounds- P. S. Kalsi, New Age International
11] Frontier Orbitals and Organic Chemical Reactions-I. Fleming
12] Orbital Symmetry – R. E. Lehr and A. P. Marchand
13] Reactive Intermediate in Organic Chemistry-N. S. Isaacs
14] Stereochemistry of Carbon Compounds- E. L. Eliel
15] Physical Organic Chemistry-J. Hine
16] Name Reaction in Organic chemistry –Surrey
17] Advanced Organic Chemistry – L. F. Fieser and M. Fieser.
18] Organic Chemistry Vol. I and II - I. L. Finar
19] Modern Organic Chemistry- J.D. Roberts and M. C. Caserio
20] The Search for Organic Reaction Pathways (Longmann), Peter Skyes
21] Organic Chemistry 5th Edition (McGraw Hill), S. H. Pine
22] Organic Chemistry (Willard Grant Press Botcon), John Mcmurry
23] A Textbook of Organic Chemistry- R. K. Bansal New Age International
24] New Trends in Green Chemistry –V. K. Ahluwalia and M. Kidwai, Anamaya publishers New Delhi
25] Organic Chemistry, J. Clayden, N. Greeves, S. Warren and P. Wothers, Oxford University Press
26] Organic Chemistry, 4th Edition, G Marc Loudon, Oxford University Press
27] Nano Materials 2007, A. K. Bandyopadhyay, New Age International
UNIT I: FORMULATION OF QUANTUM MECHANICS 15h
A] Introduction of quantum mechanics, wave function, acceptability of wave functions, normalized and
orthogonal wave functions, operators, properties of operators, eigen functions and eigen values, Hermitian
operators, orbital and generalized angular momentum, eigen function and eigen values of angular
momentum, postulates of quantum mechanics, (problems on operators, eigen values and average value)
B] Application of Schrodinger wave equation to simple systems: degeneracy in 3-dimensional box, rigid
rotator, potential well of finite depth (tunneling effect), simple harmonic oscillator, the Hydrogen atom.
UNIT II: CLASSICAL THEMODYNAMICS 15h
A] Exact and inexact differentials, condition of exactness, Pfaff differential expression, derivation of
thermodynamic equation of state, extensive and intensive properties. Homogeneous functions of degree 0
and 1. Maxwell’s relations.
B] Third law of thermodynamics, unattainability of absolute zero, calculation of entropy, residual entropy and
its application. Varial equation, fugacity, determination of fugacity.
C] Partial molar quantities: Determination of partial molar quantities, chemical potential, escaping tendency,
partial molar volume, Gibbs Duhem equation, Gibbs Duhem Mergules equation, reaction potential, Extent of
reaction (Xi).
UNIT III: PHASE EQUILIBRIA 15h
Phase rule, calculation of degrees of freedom, reduced phase rule, construction of phase diagram, one
component systems: Helium, carbon, two component systems forming solid solutions having congruent and
incongruent melting point, partially miscible solid phase, three component systems, graphical presentation,
influence of temperature, systems with 1, 2, 3 pairs of partially miscible liquids, transition points, 1st and 2nd
order phase transition, lambda line
UNIT IV: CHEMICAL KINETICS 15h
A] Theories of reaction rates: Unimolecular reactions, bimolecular reactions, collision theory, steric factor,
temperature effect on reaction rates, Arrhenius equation and its limitations, activation energy, transition
state theory, steady state approximation, Lindeman-Hinshelwood mechanism, RRKM theory
B] Photochemistry: Introduction, quantum yield, photosensitizers, quenching, kinetics of anthrascene
reactions, H2-Br2 and H2-I2 reactions.
C] Catalysis: Acid- base enzymes, enzyme catalysis, Michaelis Menten equation, effect of pH and
temperature.
List of books
1. Ira .N. Levine, Quantum Chemistry, 5th edition(2000), Pearson educ., Inc.New Delhi
2. A.K.Chandra, Introductory Quantum Chemistry, 4th edition (1994), Tata Mcgraw Hill, New Delhi.
3. S.K.Dogra, S.Dogra, Physical Chemistry Through Problems.
4. M.W.Hanna, “ Quantum Mechanics in Chemistry”, Benjamin
5. L. Pualing and E. B. Wilson, Introduction to Quantum Mechanics with Applications to Chemistry, McGraw
Hill, New York (1935).
6. R.P.Rastogi R.R. Mishra 6th revised edition An Introduction to Chemical Themodynamics.
7. Principles of Physical Chemistry by Puri, Sharma and Pathania,
8. P.W.Atkins.Physical chemistry. ELBS
9. E.N.Yenemin, “ Fundamentals of Chemical Thermodynamics”, MIR Publishers.
10. F.W.Sears, “ Introdction to Thermodynamics, Kinetic Theory of Gases and statistical mechanics”.Addison
Wesley
11. G.M.Panchenkov and V.P.Labadev, “ Chemical Kinetics and catalysis”, MIR Publishing
12. E.A. Moelwyn- Hughes, “ Chemical Kinetics and Kinetics of Solutions”, Academic
9
13. K.J.Laidler, Chemical Kinetics, Third Edition (1987), Harper and Row, New York
14. J.Raja Ram and J.C.Kuriacose, Kinetics and Mechanism of Chemical Transformations MacMilllan Indian
Ltd., New Delhi (1993)
15. R.K.Prasad,” Quantum Chemistry”, Wiley.
For detailed syllabus , here is the attachment;
Attached Files
File Type: pdf Nagpur University M.Sc Chemistry Syllabus.pdf (725.9 KB, 244 views)


Quick Reply
Your Username: Click here to log in

Message:
Options

Thread Tools Search this Thread



All times are GMT +5. The time now is 02:39 PM.


Powered by vBulletin® Version 3.8.11
Copyright ©2000 - 2024, vBulletin Solutions Inc.
SEO by vBSEO 3.6.0 PL2

1 2 3 4