#1
18th June 2015, 02:32 PM
| |||
| |||
M.Sc Chemistry Syllabus of Nagpur University
I have completed Bsc Chemistry and want to take admission in M.Sc Chemistry at Nagpur University . Provide the M.Sc Chemistry Syllabus for an idea .
|
#2
19th June 2015, 08:55 AM
| |||
| |||
Re: M.Sc Chemistry Syllabus of Nagpur University
As you are looking for the M.Sc Chemistry Syllabus of Nagpur University , here I am providing same for you . Semester I CH-101: Paper I (Inorganic Chemistry) CH-102: Paper II (Organic Chemistry) CH-103: Paper III (Physical Chemistry) CH-104: Paper IV (Analytical Chemistry) CH-105: Practical-I (Inorganic Chemistry) CH-106: Practical-II (Physical Chemistry) CH-107: Seminar-I Semester II CH-201: Paper V (Inorganic Chemistry) CH-202: Paper VI (Organic Chemistry) CH-203: Paper VII (Physical Chemistry) CH-204: Paper VIII (Analytical Chemistry) CH-205: Practical-III (Organic Chemistry) CH-206: Practical-IV (Analytical Chemistry) CH-207: Seminar-II Semester III CH-301: Paper IX (Spectroscopy) CH-302: Paper X (Special I-Inorganic /Organic/ Physical/Analytical) CH-303: Paper XI (Special II-Inorganic /Organic/ Physical/Analytical) CH-304: Paper XII (Elective- Applied Analytical/ Nuclear/ Environmental /Polymer/Medicinal ) CH-305: Practical V- Special (Inorganic /Organic/ Physical/Analytical) CH-306: Practical VI–Elective (Applied Analytical/ Nuclear/ Environmental /Polymer/Medicinal) CH-307: Seminar-III Semester IV CH-401: Paper XIII (Spectroscopy) CH-402: Paper XIV (Special I-Inorganic /Organic/ Physical/Analytical) CH-403: Paper XV (Special II-Inorganic /Organic/ Physical/Analytical) CH-404: Paper XVI (Elective- Applied Analytical/ Nuclear/ Environmental /Polymer/Medicinal) CH-405: Practical VII- Special (Inorganic /Organic/ Physical/Analytical) CH-406: Practical VIII- Project CH-407: Seminar-IV Nagpur University M.Sc Chemistry Syllabus A) Stereochemistry and Bonding in Main Group Compound: 5h VSEPER-Shape of simple inorganic molecules and ions containing lone pairs, various stereo chemical rules and resultant geometry of the compounds of non-transitional elements, short coming of VSEPR model. Bent’s rule and energetics of hybridization. B) Metal – Ligand Bonding: 10h Crystal Field Theory: Splitting of d-orbital in tetragonal, square planar and trigonal bipyramid complexes. John teller effect, spectrochemical series, nephelauxetic effect. Limitaion of crystal field theory. M.O.theory for octahedral, tetrahedral & square planar complexes with and without π-bonding. Unit-II A) Metal – Ligand Equilibria in Solution: 5h Stepwise and overall formation constants; trends in stepwise formation constants; factors affecting stability of metal complexes with reference to nature of metal ion, ligand, chelate effect and thermodyanamic origin. Determination of formation constant by : (1) spectrophotometric method (Job’s and Mole ratio method) (2) Potentiometric method (Irving-Rossotti Method) B) Reaction Mechanism of Transition metal complexes: 10h Energy Profile of a reaction, reactivity of metal complexes, Inert and Labile complexes, Kinetics of Octahedral substitution: Acid hydrolysis, factors affecting acid hydrolysis, Stereochmistry of intermidiates in SN1 & SN2 , Base hydrolysis, Conjugate base mechanism, Direct and indirect evidences in favour of conjugate mechanism, Annation reaction, reaction without metal-ligand bond breaking. Unit-III: Cluster- I 15h Boron hydrides: Classification, nomenclature, structure, bonding and topology of boranes, 4-digit coding (s, t, y, x) numbers for higher boranes and their utilities. Chemistry of diboranes: Study of Metalloboranes, Carboranes and Metallocarboranes with reference to preparations and structures. Unit – IV: Cluster-II A) Metal-Metal bonds: 10h Occurrence of metal-metal bond, Classification of metal clusters, Binuclear, trinuclear, tetranuclear, pentanuclear and hexanuclear with reference to halide, oxide, alkoxide and acetate clusters. B) Isopoly, Heteropoly acids and their anions. 5h List of Books 1) S. F. A. Kettle, J. N. Murral and S. T. Teddler: Valency Theory 2) C. A. Coulson: Valency 3) J. E. Huheey :Inorganic Chemistry 4) F .A. Cottonand G. Wilkinson: Advanced Inorganic Chemistry 3rd, 5thand 6th Editions. 5) A. F. Willims: Theoretical Approach in inorganic chemistry. 6) A. Mannas Chanda: Atomic Structure and chemical Bonding 7) L. E. Orgel: An Introduction To transition metal chemistry, Ligand field theory, 2nd Edition. 8) J. J. Logowski: Modern Inorganic Chemistry 9) B.Durrant and P.J.Durrant: Advanced Inorganic Chemistry 10) J. C. Bailar: Chemistry of coordination compounds. 11) W. L. Jolly: Modern Inorganic Chemistry 12) R. S. Drago: Physical methods in inorganic chemistry. 13) Waddington: Nonaqueous solvents. 14) Sisler: Chemistry of nonaqueous solvents. 15) A. K. Barnard: Therotical Inorganic Chemistry 16) Emeleus and Sharpe: Modern Aspect of Inorganic Chemistry. 17) F. A. Cotton: Chemical Applications of Group theory. 18) Jones: Elementary Coordination chemistry. 19) B. N. Figgis: Introduction to Ligand field. 20) S. F. A. Kettle: Coordination chemistry. 21) M.C.Day and J.Selbin: Theoretical Inorganic Chemistry. 22) J. Lewin and Wilkins: Modern Coordination Chemistry. 23) Gowarikar, Vishwanathan and Sheedar: Polymer science. 24) H. H. Jattey and M. Orchin: Symmetry in chemistry. 25) D. Schonaland: Molecular Symmetry in chemistry. 26) L. H. Hall: Group theory and Symmetry in chemistry 27) H. H. Jattey and M. Orchin: Symmetry in chemistry 28) R.L.Dutta and A.Symal: Elements of magneto chemistry 29) Inorganic Chemistry 4th Edition, P.Atkins, Oxford University Press. 30) Essential Trends in Inorganic Chemistry, D.M.P.Mingos, Oxford University Press Unit-I: 15 h A] Nature and Bonding in Organic Molecule Delocalized chemical bonding, conjugation, cross conjugation, resonance, hyper-conjugation, bonding in fullerenes. Aromaticity in benzenoid and non-benzenoid compounds, alternant and non-alternant hydrocarbons Huckel’s rule, energy level of π-molecules orbitals, annulenes, antiaromaticity, homoaromoaticity. Aromatic character and chemistry of cyclopentadienyl anion, tropylium cation, tropone and tropolone. Bonds weaker than covalent-addition compounds, crown ether complexes and cryptands, inclusion compounds, cyclodextrins, catenanes and rotaxanes B] Synthetic applications of enamines and imines anions in organic synthesis, phase transfer catalysis, crown ethers and graphene. Unit-II: 15 h A] Streochemistry Conformational analysis of cycloalkanes (5 – 8 membered rings), substituted cyclohexanes , mono substituted, disubstituted and trisubstituted cyclohexanes, decalines, effect of conformation on reactivity, Cahn-Ingold-Prelog System to describe configuration at chiral centers . Elements of symmetry, chirality, molecules with more than one chiral center, meso compounds, threo and erythro isomers, method of resolution, optical purity, enantiotopic and distereotopic atoms, groups and faces, prochirality, additionelimination reactions, stereospecific and steroselective synthesis. Asymmetrical synthesis, optical activity in absence of chiral carbon (biphenyl and allenes) B] Reactive Intermediates Generation, structure, stability and chemical reactions involving classical and non-classical carbocations, carbanions, free radical, carbenes, nitrenes and arynes. Singlet oxygen, it’s generation and reactions with organic substrates. Unit-III: 15 h A] Reaction mechanism: Structure and Reactivity Types of mechanism, Types of reaction, thermodynamics and kinetics requirements, kinetic and thermodynamic control, Hammond’s postulate, Curtin-Hammeett principle, Potential energy diagrams, transition states and intermediates, methods of determining mechanisms, isotope effects. Hard and soft acids and bases. 6 Effect of Structure on reactivity: Resonance and field effects, Steric effect, quantitative treatment. The Hammett equation and linear free energy relationship, substituent and reaction constants. Taft Equation. B] Concept of neighboring group participation (anchimeric assistance) with mechanism, neighboring group participation by π and σ bonds, classical and non classical carbocations, Intramolecular displacement by hydrogen, oxygen, nitrogen, sulphur and halogen. Alkyl, cycloalkyl, aryl participation, participation in bicyclic system, migartory aptitude, carbocation rearrangements and related rearrangements in neighboring group participation. Unit IV: 15h A] Aliphatic nucleophilic substitution The SN1, SN2, mixed SN1, SN2 and SET and SNi mechanisms. Nucleophilicty, effect of leaving group, ambient nucleophiles and ambient substrates regiospecificity, substitution at allylic and vinylic carbon atoms. B] Aromatic electrophilic substitution The arenium ion mechanism, orientation and reactivity, energy profile diagrams. The o/p ratio, ipso attack, orientation in benzene ring with more than one substituents, orientation in other ring system. Diazonium coupling, Vilsmeir reaction, Gatterman-Koch reaction, Pechman reaction, Reimer-Tieman reaction, Diazonium coupling. C] Aromatic Nucleophilic Substitution A general introduction to different mechanisms of aromatic nucleophilic substitution SNAr, SN1, benzyne and SRN1 mechanisms. Reactivity - effect of substrate structure leaving group and attacking nucleophile. The Von Richter, Sommlet-Hauser and Smiles rearrangements. List of books 1] Advanced Organic Chemistry –Reaction mechanism and structure. Jerry March, John Wiley 2] Advanced Organic Chemistry- F.A. Carey and R. J. Sunberg, Plenum 3] A Guidebook to Mechanism in Organic Chemistry-Peter Skyes, Longman 4] Structure and Mechanism in Organic Chemistry-C.K. Gold, Cornell University Press 5] Organic Chemistry, R.T. Morrison Boyd. Prentice Hall 6] Modern Organic Chemistry-H.O. House, Benjamin 7] Principal of Organic Chemistry-R.O.C. Norman and J.M. Coxon, Blackie Academic and Professional 8] Reaction Mechanism in Organic Chemistry-S.M. Mukharji and S.P. Singh, Macmilan 9] Stereochemistry of Organic Compounds- D. Nasipuri, New Age International 10] Stereochemistry of Organic Compounds- P. S. Kalsi, New Age International 11] Frontier Orbitals and Organic Chemical Reactions-I. Fleming 12] Orbital Symmetry – R. E. Lehr and A. P. Marchand 13] Reactive Intermediate in Organic Chemistry-N. S. Isaacs 14] Stereochemistry of Carbon Compounds- E. L. Eliel 15] Physical Organic Chemistry-J. Hine 16] Name Reaction in Organic chemistry –Surrey 17] Advanced Organic Chemistry – L. F. Fieser and M. Fieser. 18] Organic Chemistry Vol. I and II - I. L. Finar 19] Modern Organic Chemistry- J.D. Roberts and M. C. Caserio 20] The Search for Organic Reaction Pathways (Longmann), Peter Skyes 21] Organic Chemistry 5th Edition (McGraw Hill), S. H. Pine 22] Organic Chemistry (Willard Grant Press Botcon), John Mcmurry 23] A Textbook of Organic Chemistry- R. K. Bansal New Age International 24] New Trends in Green Chemistry –V. K. Ahluwalia and M. Kidwai, Anamaya publishers New Delhi 25] Organic Chemistry, J. Clayden, N. Greeves, S. Warren and P. Wothers, Oxford University Press 26] Organic Chemistry, 4th Edition, G Marc Loudon, Oxford University Press 27] Nano Materials 2007, A. K. Bandyopadhyay, New Age International UNIT I: FORMULATION OF QUANTUM MECHANICS 15h A] Introduction of quantum mechanics, wave function, acceptability of wave functions, normalized and orthogonal wave functions, operators, properties of operators, eigen functions and eigen values, Hermitian operators, orbital and generalized angular momentum, eigen function and eigen values of angular momentum, postulates of quantum mechanics, (problems on operators, eigen values and average value) B] Application of Schrodinger wave equation to simple systems: degeneracy in 3-dimensional box, rigid rotator, potential well of finite depth (tunneling effect), simple harmonic oscillator, the Hydrogen atom. UNIT II: CLASSICAL THEMODYNAMICS 15h A] Exact and inexact differentials, condition of exactness, Pfaff differential expression, derivation of thermodynamic equation of state, extensive and intensive properties. Homogeneous functions of degree 0 and 1. Maxwell’s relations. B] Third law of thermodynamics, unattainability of absolute zero, calculation of entropy, residual entropy and its application. Varial equation, fugacity, determination of fugacity. C] Partial molar quantities: Determination of partial molar quantities, chemical potential, escaping tendency, partial molar volume, Gibbs Duhem equation, Gibbs Duhem Mergules equation, reaction potential, Extent of reaction (Xi). UNIT III: PHASE EQUILIBRIA 15h Phase rule, calculation of degrees of freedom, reduced phase rule, construction of phase diagram, one component systems: Helium, carbon, two component systems forming solid solutions having congruent and incongruent melting point, partially miscible solid phase, three component systems, graphical presentation, influence of temperature, systems with 1, 2, 3 pairs of partially miscible liquids, transition points, 1st and 2nd order phase transition, lambda line UNIT IV: CHEMICAL KINETICS 15h A] Theories of reaction rates: Unimolecular reactions, bimolecular reactions, collision theory, steric factor, temperature effect on reaction rates, Arrhenius equation and its limitations, activation energy, transition state theory, steady state approximation, Lindeman-Hinshelwood mechanism, RRKM theory B] Photochemistry: Introduction, quantum yield, photosensitizers, quenching, kinetics of anthrascene reactions, H2-Br2 and H2-I2 reactions. C] Catalysis: Acid- base enzymes, enzyme catalysis, Michaelis Menten equation, effect of pH and temperature. List of books 1. Ira .N. Levine, Quantum Chemistry, 5th edition(2000), Pearson educ., Inc.New Delhi 2. A.K.Chandra, Introductory Quantum Chemistry, 4th edition (1994), Tata Mcgraw Hill, New Delhi. 3. S.K.Dogra, S.Dogra, Physical Chemistry Through Problems. 4. M.W.Hanna, “ Quantum Mechanics in Chemistry”, Benjamin 5. L. Pualing and E. B. Wilson, Introduction to Quantum Mechanics with Applications to Chemistry, McGraw Hill, New York (1935). 6. R.P.Rastogi R.R. Mishra 6th revised edition An Introduction to Chemical Themodynamics. 7. Principles of Physical Chemistry by Puri, Sharma and Pathania, 8. P.W.Atkins.Physical chemistry. ELBS 9. E.N.Yenemin, “ Fundamentals of Chemical Thermodynamics”, MIR Publishers. 10. F.W.Sears, “ Introdction to Thermodynamics, Kinetic Theory of Gases and statistical mechanics”.Addison Wesley 11. G.M.Panchenkov and V.P.Labadev, “ Chemical Kinetics and catalysis”, MIR Publishing 12. E.A. Moelwyn- Hughes, “ Chemical Kinetics and Kinetics of Solutions”, Academic 9 13. K.J.Laidler, Chemical Kinetics, Third Edition (1987), Harper and Row, New York 14. J.Raja Ram and J.C.Kuriacose, Kinetics and Mechanism of Chemical Transformations MacMilllan Indian Ltd., New Delhi (1993) 15. R.K.Prasad,” Quantum Chemistry”, Wiley. For detailed syllabus , here is the attachment; |
|