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16th June 2015, 03:25 PM
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Jamia Millia Islamia Chemistry
Can you please give here syllabus of MSC. Chemistry course of Jamia Millia Islamia university ?
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16th June 2015, 04:40 PM
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Re: Jamia Millia Islamia Chemistry
As you want I am here providing you syllabus of MSC. Chemistry course of Jamia Millia Islamia university. Syllabus : Semester 1 : Inorganic Chemistry-I Elements of Materials Chemistry Stereochemistry and Role of Bonding in Organic Reactions Thermodynamics Group Theory and Spectroscopy – I Title Inorganic Chemistry Lab-I Materials Chemistry Lab-I Organic Chemistry Lab-I Physical Chemistry Lab-I Semester 2 : Inorganic Chemistry-II Defects, Deformation and Deterioration of Materials Organic Reactive Inte Mechanism and Pericyclic Reactions Surface Chemistry Group Theory and Spectroscopy – II Title Inorganic Chemistry Lab-II Materials Chemistry Lab-II Organic Chemistry Lab-II Physical Chemistry Lab-II Semester 3 : Chemical Applications of Group Theory Inorganic Reaction Mechanism Organometallic Chemistry-I Bio-inorganic Chemistry – I Inorganic Chemistry Lab-III Conventional Ceramics Basic Concepts of Crystallography and Crystal Structures Polymer Chemistry and Technology Chemistry of Advanced Materials Materials Chemistry Lab-III Medicinal Chemistry Chemistry of Natural Products – I Methods in Organic Synthesis Applications of Spectroscopy – I Organic Chemistry Lab-III Nuclear Chemistry Advanced Solid State Chemistry Electrochemistry Molecular Reaction Dynamics and Catalysis M.Sc. CHEMISTRY – SEMESTER I INORGANIC CHEMISTRY PAPER – I INORGANIC CHEMISTRY – I 12 hours Unit I: Metal Ligand Equilibria in Solution Stepwise and overall formation constants and their interaction, trends in stepwise constants, factors affecting the stability of metal complexes with reference to the nature of metal ion and ligand, chelate Effect and its thermodynamic origin, determination of binary formation constants by pH-metry and Spectrophotometry. Unit II: Non–Aqueous Solvents Role of Solvents in chemical reactions, physical properties of a solvent, types of solvent and their general characteristics, reactions in non-aqueous solvents with reference to liquid ammonia and liquid SO2. Unit III: Magnetic Properties of Transition Metal Complexes Magnetic properties of transition metal complexes and lanthanides, spin-orbit coupling and susceptibility of transition metal ions and rare earths; magnetic moments of metal complexes with crystal field terms of A, E and T symmetry, T.I.P., intramolecular effects, antiferromagnetism and ferromagnetism of metal complexes, super paramagnetism. High and low spin equilibria, anamolous magnetic moments, magnetic exchange coupling and spin Crossover. Unit IV: Inorganic Materials Introduction to the solid state, metallic bond, band theory (zone model, brillouin zones, limitation of zone model): defects in solids, p-type and n-type, inorganic semiconductors (use in transistors, IC etc.), electrical, optical, magnetic and thermal properties of inorganic materials, superconductors, with special emphasis on the synthesis and structure of high temperature super conductors. Books Suggested: 1. Inczedy, J. Analytical applications of complex equilibria Halsted Press: New York, NY (1976). 2. Hartley, F. R., Burgess, C. & Alcock, R. M. Solution Equilibria Prentice-Hall: Europe (1980). 3. Ringbom, A. Complexation in Analytical Chemistry Wiley: New York (1963). 4. Non-aqueous Solution Chemistry by H.H. Sisler. 5. Magnetochemistry by R.L. Carlin. 6. Mabbs, F. E. & Machin, D. J. Magnetism and Transition Metal Complexes Chapman and Hall: U.K. (1973). 2 7. Elements of Chemistry by N. N. Greenwood and A. Earnshaw. 8. Keer, H.V. Principles of the solid state Wiley Eastern Ltd.: New Delhi (1993). 9. West, A.R. Solid State Chemistry and its Applications John Wiley & Sons (1987). 10. Cheetham, A. K. & Day, P., Eds. Solid State Chemistry Techniques Clarendon Press, Oxford (1087). MATERIALS CHEMISTRY PAPER – II ELEMENTS OF MATERIALS CHEMISTRY Unit I: Multiphase Materials 12 Lectures Introduction, solid solutions, interstitial and substitutional solid solutions, complex solid solutions intermetallic compounds, condensed phase rule, one component system Si and Fe. Binary isomorphous system: Cu-Ni, Au-Cu, Hume Rothery solid solubility rule, Liver Rule, Invarient phase Equilibrium Entetic formation (Pb-Sn) peritectic formation Fe-Ni, Fe-C phase diagram, phase transformation in Fe-C alloys, Ferrous and nonferrous alloys. Unit II: Polymer Chemistry 14 Lectures Classification of Polymers; Degree of Polymerization General Characteristics of Chain Growth Polymerization; Alkene Polymerization by Free Radical, Cationic and Anionic Initiators; General Characteristics of Step Growth Polymerization; Synthesis of Polymers by Step Growth Polymerization: Polyesters, Polyamides, Polycarbonates, Polysulphones, Polyphenyl Oxides and Polysiloxanes Ring-opening Polymerization of Ethers and Lactones Unit III: Glasses 8 Lectures General features, Fabrication of glass, Factors that influence glass formation , Viscosity, Effect of electronegativity, and bond types on oxide glass, Zachariason’s, Sun and Rawson criteria, Methods of glass formation, Silicate glasses, Pyrex glass, Phosphate glasses, Borate glasses, Thermodynamics of glass formation, Chalcogenide Glasses. Unit IV: Nanomaterials 14 Lectures Nanoscale Regime, Nano particle, Nanoporous materials, Gas phase Nanoparticles, Condensed Phase Nano Partcles, Inorganic Nano Particles, Semi conductors, Dielectric (insulator) Nano particles, Properties of nanoparticles ( Physical, mechanical, chemical, magnetic, optical and electronic properties)Method of Preparation:- Bottom Dowuard Bottom approach, metal atom aggregation in inert gases and cold matrice (GEM, PCB, CFCB and SMAD process), Sonocative Decomposition of metal carbonyl, Borohydrated Reduction, Alkali metal reduction, Zeolite Method, Emulsion, inverse micelles , Sol-Gel Methods , Co-Precipitation Method. Books Suggested: 1. Text Book of Polymer Science by F. W. Billmeyer 2. Materials Science and Engineering: An Introduction, W.D. Callister, Wiley 4 3. Principle of solid state, H. V. Keer, Wiley Eastern. 4. Chemistry of Advanced Materials by Leonard V.Interrante and M.J.Hampden-Smih ORGANIC CHEMISTRY PAPER – III STEREOCHEMISTRY AND ROLE OF BONDING IN ORGANIC REACTIONS Unit I: Configurational Isomerism Stereoisomerism: Classification, optical activity and chirality resolution of racemic mixture, molecules with one, two or more chiral centres; Fischer’s projection formula, Relative and absolute configurations, D L, R S, and E Z system of naming. Stereochemistry due to the presence of perpendicular dissymmetric planes in allenes, spiranes, biphenyls and binaphthols. Chirality due to helical shape, Optical purity, % enantiomeric excess (ee), Enantiotopic and Diastereotopic atoms groups and faces, Stereospecific and stereoselective syntheses. Unit II: Conformational Analysis Conformation in open chain system (with reference to 1,2-disubstituted ethane). Baeyer’s strain theory of cyclic compounds, conformations and stability of cyclohexanes (mono-, di- and tri- substituted). Confomation of rings containing sp2 hybridized carbon atoms, conformation of sugars. Locking groups - t-butyl groups, decalins and steroids, Effect of conformation on reactivity. Unit III: Nature of Bonding in Organic Molecules Huckel’s rule of aromaticity, annulenes, benzoid and non-benzoid aromatic systems; tropones, tropolones, azulene, pentalene and heptalene. Anti-aromaticity and Homo-aromaticity, PMO approach. Alternant and nonalternant hydrocarbons, Mesoionic compounds and squaric acid. Bonds weaker than covalent bonds, crown ether complexes and cryptands; inclusion compounds- Cyclodextrins, catananes and rotaxanes. Unit IV: Addition to Carbon-Hetero Multiple Bonds Mechanism of metal hydride reduction of saturated and unsaturated carbonyl compounds, acids, esters and nitriles. Addition of Grignard reagents, Organozinc and Organolithium reagents to carbonyl and unsaturated carbonyl compounds. Wittig Reaction. Mechanism of condensation reactions involving enolates – Aldol addition/condensation, Knoevenagel condensation, Stobbe condensation, Claisen condensation, Mannich reaction, Benzoin condensation and Perkin reaction. Hydrolysis of esters and amides, Ammonolysis of esters. Books Suggested: 1. Advanced Organic Chemistry; Jerry March, Fourth edition, Wiley & Sons, (2005). 2. Mechanisms in Organic Chemistry; Peter Sykes, Sixth edition, Pearson, (2004). 3. Organic Chemistry; Solomons & Fryhle, Eighth edition, Wiley & Sons, (2007). 4. Organic Chemistry; Clayden, Greeves, Warren and Wothers; Oxford University Press, (2006). 5. Organic Chemistry; G. Marc Louden, Fourth edition, Oxford University Press, (2006). 6. Organic Chemistry; Paula Yurkanis Bruice, Third edition, Pearson, (2004). 7. Advanced Organic Chemistry; Francis A. Carey and Richard J. Sundberg, Part A & Part B Fourth edition, Kluwer Academics/Plenum Publishers, (2001). 8. Reaction Mechanisms in Organic Chemistry; S. M. Mukherji & S. P. Singh, Macmillan, (2004). 9. Organic Reactions, Stereochemistry and Mechanisms; P.S. Kalsi, Fourth edition, New Age International Publishers, (2006). 10. Eliel, E. L. Stereochemistry of Carbon Compounds Textbook Publishers (2003). 11. Bruckner, R. Advanced organic chemistry Elsevier(2002). 12. Lowry, T. H. & Richardson, K. S. Mechanism and Theory in Organic Chemistry Addison-Wesley Educational Publishers, Inc. (1981). Here is the attachment. |