Guru Jambheshwar university of Science and Technology Ph. D Chemistry Entrance Questi

Can you provide me the syllabus of Ph. D Chemistry Entrance Test of Guru Jambheshwar University of Science and Technology on which the question paper is based?

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The syllabus of Ph. D Chemistry Entrance Test of Guru Jambheshwar University of Science and Technology on which the question paper is based is as follows:

Inorganic Chemistry
1. Chemical periodicity
2. Structure and bonding in homo- and heteronuclear molecules, including shapes of molecules (VSEPR Theory).
3. Concepts of acids and bases, Hard-Soft acid base concept, Non-aqueous solvents.
4. Main group elements and their compounds: Allotropy, synthesis, structure and bonding, industrial importance of the compounds.
5. Transition elements and coordination compounds: structure, bonding theories, spectral and magnetic properties, reaction mechanisms.
6. Inner transition elements: spectral and magnetic properties, redox chemistry, analytical applications.
7. Organometallic compounds: synthesis, bonding and structure, and reactivity. Organometallics in homogeneous catalysis.
8. Cages and metal clusters.
9. Analytical chemistry- separation, spectroscopic, electro- and thermoanalytical methods.
10. Bioinorganic chemistry: photosystems, porphyrins, metalloenzymes, oxygen transport, electron- transfer reactions; nitrogen fixation, metal complexes in medicine.
11. Characterisation of inorganic compounds by IR, Raman, NMR, EPR, Mössbauer, UV-vis, NQR, MS, electron spectroscopy and microscopic techniques.
12. Nuclear chemistry: nuclear reactions, fission and fusion, radio-analytical techniques and activation analysis.
Physical Chemistry:
1. Basic principles of quantum mechanics: Postulates; operator algebra; exactly-
solvable systems: particle-in-a-box, harmonic oscillator and the hydrogen atom, including shapes of atomic orbitals; orbital and spin angular momenta; tunneling.
2. Approximate methods of quantum mechanics: Variational principle; perturbation theory up to second order in energy; applications.

3. Atomic structure and spectroscopy; term symbols; many-electron systems and antisymmetry principle.

4. Chemical bonding in diatomics; elementary concepts of MO and VB theories; Huckel theory for conjugated π-electron systems.

5. Chemical applications of group theory; symmetry elements; point groups; character tables; selection rules.

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