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30th June 2017, 03:47 PM
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Join Date: Aug 2012
Re: Utkal University PG Entrance Syllabus

AS you want syllabus of PG Entrance Exam conducted by Utkal University for admission in M.SC Chemistry Course, so here I am providing syllabus:

Utkal University M.SC Chemistry Entrance Exam Syllabus

1. Reactions and reagents: Organometallic compounds-Grignard reagent-synthesis of different types of compounds like alcohol, aldehyde, acid, amine and organometallic. Acetoacetic ester-tautomerism-base hydrolysis-acid hydrolysis-malonic ester-cyano acetic ester-synthesis of dicarboylic acids and unsaturated acids.

2. Carbohydrates: R, S, configuration, mutarotation, conversions-glucose to fructose and vice versa, sucrose-structural elucidation, extraction, reactions, starch and cellulose-structural details, applications

3. Alicyclic compounds, aromatic compounds, fats and oils: Alicyclic compounds-nomenclature-synthesis of alicyclic compounds using carbon-acroyloin condensation-Diels Alder reaction, Freundss synthesis-bayer's strain theory postulates, drawbacks-theory of strainless rings-conformations of cyclohexane. Coal tar distillation, separation of benzene, toluene, phenol and naphthalene – Aromaticity exhibited by these compounds. Fats and oils-Saponification-hydrogenation of oils

4. Amino acids, proteins and dyes: Amino acids and proteins-classification-synthesis of amino acids-reactions of carboxyl group and amino group-peptide linkage-end group analysis-colour reaction of proteins-denaturation. Dyes-colors and constitution-chromophores and auxochromes-Quinine theory and electron theory of dyes-preparation-colour and application of azodyes-acidic. basic, mordant, direct azodyes-Triphenylmethane dyes-malachite green, crystal violet, Rosaniline, prosaniline mordant dyesapplication, vat dyes-indigo-synthesis and application

5. Heterocyclic compounds and natural products: Heterocyclic compounds-synthesis and reaction of pyrrole ,furan ,thiophene, pyridine, quinine, isoquinoline. Alkaloids-Isolation from natural products-colour reaction-structural elucidation of nicotine. Terpenoids-Isolation-Isoprene rule-structural elucidation of citral.

6. Polymer: Nomenclature, functionality, classification, methods of polymerization, mechanism of polymerization, molecular weight determination-Viscometry, light scattering methods. Plastics-Moulding constituents of a plastics and moulding of plastics into articles. Important thermoplastics and thermosetting resins-synthesis & applications of PVA, 23 FLUON, PC, Kevlar, ABS polymer, phenolic & amino resins, epoxy resins and polyurethanes. Conductive polymers.

7. Nucleophilic substitution: Reactivity, structural and solvent effects, substitution in SN1, SN2, SNi. Neighbouring group participation -Norbornyl and bridgehead systems, substitution at allylic and vinylic carbons, substitution by ambident nucleophiles, aromatic nucleophilic substitution, SN Ar, benzyne, SN1. Aromatic nucleophilic substitution of activated halides

8. Elimination reactions: E1, E2, E1CB-mechanism, stereochemistry, orientation of double bonds-Hoffmann, Zaitsev, Bredts rule-pyrolytic elimination, Chugaev reaction. Oxidation and reduction: Reduction using hydride reagents, LiAlH4, NABH4 and other organoboranes: chemo-and stereoselectivity, catalytic hydrogenation (homogenous and heterogeneous catalysts), Swern and DessMartin oxidations, Corey-Kim oxidation, PCC, KMnO4 oxidations.

9. Theories of aromaticity: Aromaticity, antiaromaticity, Huckels rule, annulences and heteroannulenes, fullerenes (C60). Other conjugated systems, Chichibabin reaction. Aromatic electrophilic substitution: Orientation, reactivity, and mechanisms. Substitution in thiophene and pyridine. Reactive intermediates-carbenes, nitrenes, radicals, Ylides-Formation, stability and their applications.

10. Addition to carbon-carbon multiple bonds: Electrophilic, nucleophilic and free radical addition. Stereochemistry and orientation of the addition. Hydrogenation, halogenation, hydroxylation, hydroboration. Addition to carbonyl compounds-1,2 and 1,4-addition, benzoin, Knoevenegal, Stobbe and Darzen glycidic ester reactions.

Utkal University M.SC Chemistry Entrance Exam Syllabus



Last edited by pawan; 30th June 2017 at 03:49 PM.


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