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19th June 2015, 04:16 PM
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Join Date: Apr 2013
Re: TYBSC syllabus Mumbai University

As you are asking for the syllabus of Mumbai University for TYBSC Chemistry so here I am providing you the syllabus below for V semesters.


Course UNIT TOPICS Credits L / Week
USCH501 I

1.1 Colligative Properties of Dilute
Solutions (8L)
1.1.1 Dilute solution, colligate
properties, Raoult’s law, relative
lowering of vapour pressure.
1.1.2 Elevation in boiling point of a
solution, thermodynamic derivation
relating elevation in the boiling point
of a solution and the molar mass of the
non-volatile solute.
1.1.3 Depression in freezing point of a
solution, thermodynamic derivation
relating the depression in the freezing
point of a solution and the molar mass
of the non-volatile solute.
1.1.4 Osmotic pressure, van’t Hoff’s
equation for osmotic pressure,
(derivation is expected) and
determination of molar mass of the
solute. Abnormal molar masses of
solutes and van’t Hoff factor
(calculation of Degree of Association
and Degree of Dissociation.)
1.2 Phase Rule (7L)
1.2.1 Gibb’s phase rule and terms
involved in the equation.
1.2.2 Application of phase rule to ONE
component systems (i) water system,
(ii) sulphur system
1.2.3 Application of phase rule to
TWO component systems, condensed
systems, condensed phase rule, eutectic
systems (Lead-Silver system),
desilverisation of lead.
1.2.4 Introduction to three component
system, explanation of phase diagram
for three liquids forming one
immiscible pair.
2.5 1

II
2.1 Surface Chemistry & Catalysis
(9L)
2.1.1 Adsorption: Physical and
Chemical Adsorption, types of
adsorption isotherms . Langmuir’s
adsorption isotherm (Postulates and
derivation expected). B.E.T. equation
for multilayer adsorption, (derivation
not expected). significance of the terms
involved in the equation is
expected.),determination of surface
area of an adsorbent using B.E.T.
equation. Numericals on surface area
determination are expected.
2.1.2 Catalysis: Homogeneous and
heterogeneous catalysis, catalytic
activity and selectivity, promoters,
inhibitors, catalyst poisoning and
deactivation,
2.1.3 Acid-Base catalysis, mechanism
and kinetics of acid-base catalyzed
reactions, effect of pH on acid-base
catalyzed reactions. Mechanism and
kinetics of enzyme catalyzed reaction
(Michaelis-Menten equation).
2.2 Colloids (6L)
2.2.1 Introduction to colloidal state of
matter.
2.2.2 Origin of charge on colloidal
particles. Concept of electrical double
layer, zeta potential, Helmholtz and
Stern model, Electro-kinetic
phenomena:1.Electrophoresis
,2.Electrophoresis ,3. Streaming
potential 4. Sedimentation potential .
2.2.3 Colloidal electrolytes.
2.2.4 Donnan Membrane Equilibrium.
2.2.5 Surfactants, micelle formation,
applications of surfactants in
detergents, food industry, in pesticide
formulations.

III
3.1 Electrochemistry –
Electrochemical cells (15L)
3.1.1 Lewis concept of Activity and
Activity coefficient, Mean ionic
activity and mean ionic activity
coefficient γ+- of an electrolyte,
expression for activities of electrolytes
of different valence type, ionic strength
of a solution, Debye-Huckel limiting
law (derivation not expected)
1
3.1.2 Classification of cells: 1.chemical
cells without transference
2.Concentration cells with and without
transference (derivations of
expression for concentration cell EMF
are expected) Origin of liquid-liquid
junction potential and its elimination
using a salt bridge.
3.1.3 Applications of EMF
.measurements in the determination
of 1. pH of a solution using
quinhydrone and glass electrode. 2
solubility and solubility product of
sparingly soluble salts using chemical
cell and concentration cell method 3.
determination of liquid-liquid junction
potential .


IV
4.1 Introduction to Polymers (8L)
4.1.1 Basic terms : macromolecule,
monomer, repeat unit, degree of
polymerization.
4.1.2. Classification of polymers
based on (i) source, (ii) structure, (iii)
thermal response, (iv) physical
properties.
4.1.3. Molar masses of polymers: 1.
Number average molar mass, 2.Weight
average molar mass, 3. Viscosity
average molar mass, monodispersity,
polydispersity.
4.1.4. Methods of determining molar
masses of polymers : 1. Ultrcentrifuge
method ( Limiting velocity method
only). Viscosity method ( Mark-
Houwink equation).
4.1.5. Introduction to light emmiting
polymers ( characteristics, method of
preparation and it’s application are
expected ).
4.2 Crystalline State (7L)
4.2.1. Laws of Crystallography
4.2.2. Characteristics of simple cubic,
face centered and body centered cubic
system, inter planar distance in cubic
lattices ( only expressions for ratios of
inter planar distances are expected ).
4.2.3. Use of X- rays in the study of
crystal structure, Bragg’s equation (
derivation expected), X- ray diffraction
method of studying crystal lattices,
structure of NaCl and KCl,
1
determination of Avagadro number.
4.2.4. Elementary idea of defects in
crystals- Frenkel defect and Schottky
defect.

For more detals I am attaching the pdf.

Contact Details:
University of Mumbai
CST Road, Kalina, Santacruz East,
Mumbai, Maharashtra 400098
Phone: 022 2654 3000

[MAP]University of Mumbai[/MAP]
Attached Files
File Type: pdf Syllabus of TYBSC Chemistry of Mumbai University.pdf (216.4 KB, 381 views)


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