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  #2  
1st February 2013, 09:02 AM
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Join Date: May 2012
Re: Mumbai University MSC Organic Chemistry Question Paper

I have Mumbai University M.Sc. Chemistry course syllabus in which Organic Chemistry course a chapter and here is its syllabus:

Course Code ––(Inorganic Chemistry) PSCH 102
[Total Lectures 60 L]
Unit - I
Topic - Inorganic Reaction Mechanisms
[15L]
(i) Rate of reactions, factors affecting the rate of reactions, techniques for determination of rate of reaction.
(ii) Ligand substitution reactions of (a) octahedral complexes without breaking of metal- ligand bond, (b) square planar complexes – trans-effect, its theories and applications. Mechanism and factors affecting these substitution reactions and (c) Tetrahedral complexes.
(iii) Redox reactions: electron and atom transfer reactions, inner and outer sphere mechanisms, Marcus theory, complimentary and non complimentary reactions.
(iv) Isomerization and racemization reactions.

Unit – II
Topic - Organometallic Chemistry
[15 L]
(i) Organometallic compounds of transition metals: Preparation and properties of the following organometallic compounds: (a) Alkyl and Aryl derivatives, (b) Carbenes and Carbynes, (c) Alkene complexes, (d) Alkyne complexes, (e) Allyl complexes,
(f) Cyclopentadiene complexes and (g) Arene complexes (sandwich and half sandwich complexes).

For complete syllabus you are free to download attached pdf file.
Attached Files
File Type: pdf Mumbai University MSc Chemistry Syllabus.pdf (159.5 KB, 239 views)
  #3  
18th March 2014, 06:51 PM
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Re: Mumbai University MSC Organic Chemistry Question Paper

Quote:
Originally Posted by maxipq View Post
Provide me MSC Organic Chemistry Question Paper sem 3/syllabus of Mumbai University.
please give me m.sc. sem 3 organic chemistry question papre
  #4  
27th October 2014, 08:52 AM
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Re: Mumbai University MSC Organic Chemistry Question Paper

Old question papers MSc-1 chemistry of Mumbai university
  #5  
7th November 2019, 02:36 PM
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Re: Mumbai University MSC Organic Chemistry Question Paper

Can you provide me the syllabus of 2nd year M.Sc. Organic Chemistry Program offered by University of Mumbai on which the question paper is based?
  #6  
7th November 2019, 02:40 PM
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Join Date: Aug 2012
Re: Mumbai University MSC Organic Chemistry Question Paper

The syllabus of 2nd year M.Sc. Organic Chemistry Program offered by University of Mumbai on which the question paper is based is as follows:

M.Sc. Organic Chemistry

Semester III

Course Code: PSCHO301

Paper - I (Theoretical organic chemistry-I)

Unit 1 Organic reaction mechanisms [15L]
1.1 Organic reactive intermediates, methods of generation, structure, stability
and important reactions involving carbocations, nitrenes, carbenes, arynes
and ketenes.
[5L]
1.2 Neighbouring group participation: Mechanism and effects of anchimeric
assistance, NGP by unshared/ lone pair electrons, π-electrons, aromatic
rings, σ-bonds with special reference to norbornyl and bicyclo[2.2.2]octyl
cation systems (formation of non-classical carbocation)
[3L]
1.3 Role of FMOs in organic reactivity: Reactions involving hard and soft
electrophiles and nucleophiles, ambident nucleophiles, ambident
electrophiles, the α effect.
[2L]
1.4 Pericyclic reactions: Classification of pericyclic reactions; thermal and
photochemical reactions. Three approaches:
Evidence for the concertedness of bond making and breaking
Symmetry-Allowed and Symmetry-Forbidden Reactions
The Woodward-Hoffmann Rules-Class by Class
The generalised Woodward-Hoffmann Rule
Explanations for Woodward-Hoffmann Rules
The Aromatic Transition structures [Huckel and Mobius]
Frontier Orbitals
Correlation Diagrams, FMO and PMO approach
Molecular orbital symmetry, Frontier orbital of ethylene, 1,3 butadiene,
1,3,5 hexatriene and allyl system.
[5L]



Unit 2 Pericyclic reactions [15L]
2.1 Cycloaddition reactions: Supra and antra facial additions, 4n and 4n+2
systems, 2+2 additions of ketenes. Diels-Alder reactions, 1, 3-Dipolar
cycloaddition and cheletropic reactions, ene reaction, retro-Diels-Alder
reaction, regioselectivity, periselectivity, torquoselectivity, site selectivity
and effect of substituents in Diels-Alder reactions.
Other Cycloaddition Reactions- [4+6] Cycloadditions, Ketene
Cycloaddition, Allene Cycloadditions, Carbene Cycloaddition, Epoxidation
and Related Cycloadditions.
Other Pericyclic reactions: Sigmatropic Rearrangements, Electrocyclic
Reactions, Alder Ene Reactions.
[7L]
2.2 Electrocyclic reactions: Conrotatory and disrotatary motions, 4nπ and
(4n+2)π electron and allyl systems.
[3L]
2.3 Sigmatropic rearrangements: H-shifts and C-shifts, supra and antarafacial
migrations, retention and inversion of configurations. Cope (including oxyCope and aza-Cope) and Claisen rearrangements. Formation of Vitamin D
from 7-dehydrocholesterol, synthesis of citral using pericyclic reaction,
conversion of Endiandric acid E to Endiandric acid A.


Unit 3: Stereochemistry-I [15L]
3.1 Classification of point groups based on symmetry elements with examples
(nonmathematical treatment).
[2L]
3.2 Conformational analysis of medium rings: Eight to ten membered rings and
their unusual properties, I-strain, transannular reactions.
[3L]
3.3 Stereochemistry of fused ring and bridged ring compounds: decalins,
hydrindanes, perhydroanthracenes, steroids, and Bredts rule.
[5L]
3.4 Anancomeric systems, Effect of conformation on reactivity of cyclohexane
derivatives in the following reactions (including mechanism): electrophilic
addition, elimination, molecular rearrangements, reduction of
cyclohexanones (with LiAlH4, selectride and MPV reduction) and
oxidation of cyclohexanols.



Syllabus 2nd year M.Sc. Organic Chemistry University of Mumbai






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