#1
31st January 2013, 11:06 AM
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Mumbai University MSC Organic Chemistry Question Paper
Provide me MSC Organic Chemistry Question Paper/syllabus of Mumbai University.
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#2
1st February 2013, 09:02 AM
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Re: Mumbai University MSC Organic Chemistry Question Paper
I have Mumbai University M.Sc. Chemistry course syllabus in which Organic Chemistry course a chapter and here is its syllabus: Course Code ––(Inorganic Chemistry) PSCH 102 [Total Lectures 60 L] Unit - I Topic - Inorganic Reaction Mechanisms [15L] (i) Rate of reactions, factors affecting the rate of reactions, techniques for determination of rate of reaction. (ii) Ligand substitution reactions of (a) octahedral complexes without breaking of metal- ligand bond, (b) square planar complexes – trans-effect, its theories and applications. Mechanism and factors affecting these substitution reactions and (c) Tetrahedral complexes. (iii) Redox reactions: electron and atom transfer reactions, inner and outer sphere mechanisms, Marcus theory, complimentary and non complimentary reactions. (iv) Isomerization and racemization reactions. Unit – II Topic - Organometallic Chemistry [15 L] (i) Organometallic compounds of transition metals: Preparation and properties of the following organometallic compounds: (a) Alkyl and Aryl derivatives, (b) Carbenes and Carbynes, (c) Alkene complexes, (d) Alkyne complexes, (e) Allyl complexes, (f) Cyclopentadiene complexes and (g) Arene complexes (sandwich and half sandwich complexes). For complete syllabus you are free to download attached pdf file. |
#4
27th October 2014, 08:52 AM
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Re: Mumbai University MSC Organic Chemistry Question Paper
Old question papers MSc-1 chemistry of Mumbai university
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#5
7th November 2019, 02:36 PM
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Re: Mumbai University MSC Organic Chemistry Question Paper
Can you provide me the syllabus of 2nd year M.Sc. Organic Chemistry Program offered by University of Mumbai on which the question paper is based?
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#6
7th November 2019, 02:40 PM
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Re: Mumbai University MSC Organic Chemistry Question Paper
The syllabus of 2nd year M.Sc. Organic Chemistry Program offered by University of Mumbai on which the question paper is based is as follows: M.Sc. Organic Chemistry Semester III Course Code: PSCHO301 Paper - I (Theoretical organic chemistry-I) Unit 1 Organic reaction mechanisms [15L] 1.1 Organic reactive intermediates, methods of generation, structure, stability and important reactions involving carbocations, nitrenes, carbenes, arynes and ketenes. [5L] 1.2 Neighbouring group participation: Mechanism and effects of anchimeric assistance, NGP by unshared/ lone pair electrons, π-electrons, aromatic rings, σ-bonds with special reference to norbornyl and bicyclo[2.2.2]octyl cation systems (formation of non-classical carbocation) [3L] 1.3 Role of FMOs in organic reactivity: Reactions involving hard and soft electrophiles and nucleophiles, ambident nucleophiles, ambident electrophiles, the α effect. [2L] 1.4 Pericyclic reactions: Classification of pericyclic reactions; thermal and photochemical reactions. Three approaches: Evidence for the concertedness of bond making and breaking Symmetry-Allowed and Symmetry-Forbidden Reactions The Woodward-Hoffmann Rules-Class by Class The generalised Woodward-Hoffmann Rule Explanations for Woodward-Hoffmann Rules The Aromatic Transition structures [Huckel and Mobius] Frontier Orbitals Correlation Diagrams, FMO and PMO approach Molecular orbital symmetry, Frontier orbital of ethylene, 1,3 butadiene, 1,3,5 hexatriene and allyl system. [5L] Unit 2 Pericyclic reactions [15L] 2.1 Cycloaddition reactions: Supra and antra facial additions, 4n and 4n+2 systems, 2+2 additions of ketenes. Diels-Alder reactions, 1, 3-Dipolar cycloaddition and cheletropic reactions, ene reaction, retro-Diels-Alder reaction, regioselectivity, periselectivity, torquoselectivity, site selectivity and effect of substituents in Diels-Alder reactions. Other Cycloaddition Reactions- [4+6] Cycloadditions, Ketene Cycloaddition, Allene Cycloadditions, Carbene Cycloaddition, Epoxidation and Related Cycloadditions. Other Pericyclic reactions: Sigmatropic Rearrangements, Electrocyclic Reactions, Alder Ene Reactions. [7L] 2.2 Electrocyclic reactions: Conrotatory and disrotatary motions, 4nπ and (4n+2)π electron and allyl systems. [3L] 2.3 Sigmatropic rearrangements: H-shifts and C-shifts, supra and antarafacial migrations, retention and inversion of configurations. Cope (including oxyCope and aza-Cope) and Claisen rearrangements. Formation of Vitamin D from 7-dehydrocholesterol, synthesis of citral using pericyclic reaction, conversion of Endiandric acid E to Endiandric acid A. Unit 3: Stereochemistry-I [15L] 3.1 Classification of point groups based on symmetry elements with examples (nonmathematical treatment). [2L] 3.2 Conformational analysis of medium rings: Eight to ten membered rings and their unusual properties, I-strain, transannular reactions. [3L] 3.3 Stereochemistry of fused ring and bridged ring compounds: decalins, hydrindanes, perhydroanthracenes, steroids, and Bredts rule. [5L] 3.4 Anancomeric systems, Effect of conformation on reactivity of cyclohexane derivatives in the following reactions (including mechanism): electrophilic addition, elimination, molecular rearrangements, reduction of cyclohexanones (with LiAlH4, selectride and MPV reduction) and oxidation of cyclohexanols. Syllabus 2nd year M.Sc. Organic Chemistry University of Mumbai |