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25th July 2015, 03:49 PM
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Join Date: Apr 2013
Re: MSC Chemistry Syllabus Kota University

As you want I am here giving you syllabus for M.Sc. (Previuos) Chemistry program of Kota University.

Syllabus :

Inorganic Chemistry
Organic Chemistry
Physical Chemistry
Group Theory & Spectroscopy Mathematics for chemists or
Biology for Chemists
Computers for Chemists
Practical
Seminar (Internal)

INORGANIC CHEMISTRY

Unit-I
Stereochemistry and Bonding in Main Group Compounds
VSEPRT, Walsh diagram (tri- and penta-atomic molecules), d_-p_ bonds, Bent rule and
energetics of hybridization, some simple reactions of covalently bonded molecules.
Metal-Ligand Equilibria in Solution
Stepwise and overall formation constants and their interaction, trends in stepwise constant,
factors affecting the stability of metal complexes with reference to the nature of metal ion and
ligand. Chelate effect and its thermodynamic origin, determination of binary formation
constants by pH-metry and spectrophotometry.

Unit-II
Reaction Mechanism of Transition Metal Complexes
Energy profile of a reaction, reactivity of metal complex, inert and labile complexes, kinetic
application of valence bond and crystal field theories, kinetics of octahedral substitution, acid
hydrolysis, factors affecting acid hydrolysis, base hydrolysis, conjugate base mechanism,
direct and indirect evidences in favour of conjugate mechanism, anation reactions, reactions
without metal ligand bond cleavage. Substitution reactions in square planar complexes, the
trans effect, mechanism of the substitution reaction. Redox reaction, electron transfer
reactions, mechanism of one electron transfer reactions, outer sphere type reactions, cross
reactions and Marcus-Hush theory, inner sphere type reactions.

Unit-III
Metal-Ligand bonding
Limitation of crystal field theory, molecular orbital theory, octahedral, tetrahedral and square
planar complexes, _-bonding and molecular orbital theory.

Unit-IV
Electronic Spectra and Magnetic Properties of Transition Metal Complexes
Spectroscopic ground states, correlation. Orgel and Tanabe-Sugano diagrams for transition
metal complexes (d1-d9 states), calculations of D_, _ and _ parameters, charge transfer
spectra, spectroscopic method of assignmetnt of absolute configuration in optically active
metal chelates and their stereochemical information, anomalous magnetic moments, magnetic
exchange coupling and spin crossover.

Unit-V
A. Metal _-Complexes
Metal carboynl, structure and bonding, vibrational spectra of metal carbonyls for bonding and
structural elucidation, important reactions of metal carbonyls; preparation, bonding structure
and important reaction of transition metal nitrosyl, dinitrogen and dioxgen complexes;
tertiary phosphine as ligand.
B. Metal Clusters
Higher boranes, carboranes, metalloboranes and metallocarboranes. Metal carbonyl and
halide clusters, compounds with metal metal multiple bonds.
M.Sc. (Previuos) Chemistry Syllabus
kinetic requirements, kinetic
and thermodynamic control, Hammond's postulate, Curtin-Hammett principle. Potential
energy diagrams, transition states and intermediates, methods of determining mechanisms,
isotopes effects Generation, structure, stability and reactivity of carbocations, carbanions, free
radicals, carbenes and nitrenes. Effect of structure on reactivity, resonance and field effects,
steric effect, quantitative treatment. The Hammett equation and linear free energy
relationship, subsistent and reaction constants, Taft equation.
B. Aliphatic Nucleophilic Substitution
The SN2, SN1 mixed SN1 and SN2 and SET mechanisms. The neighbouring group mechanism,
neighbouring group participation by _ and _ bonds, anchimeric assistance. Classical and
nonclassical carbocations, phenonium ions, norbornyl systems, common carbocation
rearrangements. Application of NMR spectroscopy in the detection of carbocations. The SN1
mechanism. Nucleophilic substitution at an allylic, aliphatic trigonal and a vinylic carbon.
Reactivity effects of substrate structure, attacking nucleophile, leaving group and reaction
medium, phase transfer catalysis and ultrasound, ambident nucleophile, regioselectivity.
Unit-III
Aliphatic Electrophilic Substitution
Bimolecular mechanisms SE2 and SE1, The SE1 mechanism, electrophilic substution
accompanied by double bond shifts. Effect of substrates, leaving groups and the solvent
polarity on the reactivity.
Aromatic Electrophilic Substitution
The arenium ion mechanism, orientation and reactivity, energy profile diagrams. The
ortho/para ratio, ipso attack, orientation in other ring systems. Quantitative treatment of
reactivity in substrates and electrophiles. Diazonium coupling, Vilsmeir reactiion, Gatterman-
Koch reaction.
Aromatic Nucleophilic Substitution
The SNAr SN1, benzyne and SRN1 mechanism, Reactivity effect of substrate structure, leaving
group and attacking nucleophile. The Von Richte, Sommelet-Hauser, and Smiles
rearrangements.
Free Radical Reactions
Types of free radical reactions, free radical substitution mechanism, mechanism at an
aromatic substrate, neighbouring group assistance. Reactivity for aliphatic and aromatic
substrates at a bridgehead. Reactivity in the attacking radicals. The effect of solvents on
reactivity. Allylic halogenation (NBS), oxidation of aldehydes to carboyxlic acids, autooxidation,
coupling of alkynes and arylation of aromatic compounds by diazonium salts,
Sandmeyer reaction. Free radical rearrangement. Hunsdiecker reaction.

Address:
University of Kota
Near Kabir Circle, MBS Marg, Swami Vivekanand Nagar
Kota, Rajasthan 324005

Map:
[MAP]University of Kota Rajasthan[/MAP]
Here is the attachment;
Attached Files
File Type: pdf M.Sc. (Previuos) Chemistry Syllabus.pdf (151.0 KB, 175 views)


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