HPAS Exam Detail Information

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HPPSC is Himachal Pradesh Public Service Commission.
As you want to get HPPSC HPAS Chemistry Exam detailed syllabus so here I am giving you same:
HPPSC HPAS Chemistry Syllabus
PAPER-1
Atomic structure and chemical bonding-Quantum theory, Schrodinger equation, particle in a box,
hydrogenatom. Hydrogen moleculeion, Elements of vallence, bond and molecular orbital theory (idea of
bonding, non-bonding and antibonding orbitals) Sigma and Pibonds.
Chemical Kinetics-Kinetics of reactions involving free radicals, Kinetics of polymerization and
Photochemical reactions.
Surface Chemistry and Catalysis-Physical absorption is otherms, surface area determination,
heterogeneous catalysus acid base and enzime catalysis.
Electrochemistry-Lomic equilibra, Theory of strong electrolytes, Debye, Huckel theory of
activity coecients electrolytic conduction galvanic cells memberance equalibria and fuel cells. Electrolysis and
overvoltage.
Thermodynamics-Laws of Thermodynamics and application to physicachemical processes, systems of
variable compositions.
Electronic structure of Transition Metal Complexes-Crystal fields theory and modifications, complexes
of Piacceptor ligands, organometallic compounds of transition metals.
Lanthanides and Actinides- Separation Chemistry, Oxidation State, magnetic properties.
Reaction in non-acqueous solvents.
PAPER-II
Physical Organic Chemistry:- Electronic displacements- Inducive, electromeric, mesomeric and hyper
conjugative effects. Electrophile nucleophiles and free redicals Resonance and its application to organic
compounds. Effect of structure on the disconciation constants of organic acids and basis Hydrogen bond and its
effects on the properties of organic compounds.
Modern concepts of organic reaction mechanism- addition substitution elimination and rearrangement
reaction involving free radicals. Mechanisms of aromatic substitution. Benzene intermediates.
alipathic Chemistry:-Chemistry of simple organic compounds beloging to the following classes-alkanes
Alkynes. Alkyl halides, alcohols, thiols aldehydes, ketones, and their derivatives, eithers, amions, amine acids,
hydroxy acids, un-struated acids, dibasic acids.
Synthetical and uses of the following :
Acetoacetic and malonic esters, organometalic compounds of magnesium and lithium, ketene carbene
and diazomethane.
Carbohydrates:- Classification, configuration and general reaction or simple monosaccharides chemistry
of glucose, frustose and sucrose.
Stereo Chemistry:- Elements of symmetry and simple symmetry operation, optical and geometrical
Isomerism in simple organic molecules E.Z. and R.S. nortaions. Conformations of simple organic molecules.
Stero chemistry of inorganic co-ordination compounds.
Automatic Chemistry.- Benezene, Toluene and their helegeon, hydroxy, nitro and amini dervatives
Sulphonic acids, Zylenes,
Benzaldehyde. Salicyladehyde, acetophenone, benzonic, Pathalic saliculic, cinnamic and mandelic acids,
reduction products of nitrobenzene, Diazonium salts and their synthetic uses.
Structure, synthesis and important reactions of naphthlenes anthracene, Phenantherene, Pyridune and
quinoline.
Basic concepts regarding the following materials of economic and medical importance Cellulose and starch
coaltar, chemicals, organic polymers. Oils and fats, petrochemicals, Vitamins,hormones, alkaloids.
(fermentation products including antibiotics, proteins).
Organic Photochemistry.- Energy level diagrams, quantum yield, photochemistry of simple organic
molecules.
Polymers:- Physical chemistry of polymers, Molecular weight averages and group analysis, sedimentation
light seattering and viscoisity of polymer solution. Alloys and intermetallic.